由反应速率方程推测反应机理的经验规则

摘要

由反应速率方程推测反应机理的知识在"物理化学"教材中介绍较少, 结合应用例题介绍了由反应速率方程反推反应机理的经验规则, 并介绍了推测反应机理的一般步骤, 有助于物理化学的自学者和科研人员掌握推导机理的基础知识.%The knowledge for deducing reaction mechanism from rate law is less introduced in the textbook of physical chemistry.The empirical rules for deducing reaction mechanism from rate law were introduced as well as the general steps for deducing the reaction mechanism, which is helpful for the self-study and can provide the basic knowledge for the researcher.