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A facile and convenient method for synthesis of alkyl thiocyanates under homogeneous phase transfer catalyst conditions

机译:在均相转移催化剂条件下合成硫氰酸烷基酯的简便方法

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摘要

一个简单、环境地友好的方法用 tetrabutylammonium 溴化物(TBAB ) 为烷基卤化物的有效变换被描述到烷基 thiocyanate 为阶段转移催化剂。反应在水里发生并且在高收益供应相应烷基 thiocyanate。当反应的副产品被观察,没有进一步的纯化,产品在纯形式被获得,不为 isothiocyanates 的形成证实。
机译:A simple and environmentally friendly method is described for the efficient conversion of alkyl halide to alkyl thiocyanate using tetrabutylammonium bromide (TBAB) as a phase transfer catalyst.The reactions occur in water and furnish the corresponding alkyl thiocyanate in high yields.No evidence for the formation of isothiocyanates as by-product of the reaction was observed and the products were obtained in pure form without further purification.

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