The reaction between 2,5-Dimethylpyrrole (1) and RFI (2)(RF: a, Cl(CF2)4; b, Cl(CF2)6; c, Cl(CF2)8; d, n-C6F13; e, n-C8F17) in the presence of Na2S2O4-NaHCO3 in acetonitrile resulted in the formation of 2-perfluoroalkyl-2,5-dimethyl-2H-pyrrole (3) as a major product in good yield.
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机译:a new and convenient method for the synthesis of dehydroamino acids starting from ethyl N-Boc- and N-Z-α-tosylglycinates and various nitro compounds