The research progress on asymmetric addition reactions participating by isocyanoacetate is re-viewed.According to the type of electrophilic reagents in reactants,the advances of asymmetric addition reac-tions of isocyanoacetate with aldehydes,ketones,imines or olefins in different catalytic systems are summarized.%综述了异氰基乙酸酯参与的不对称加成反应的最新进展,按照反应物中亲电试剂的类型,介绍了异氰基乙酸酯与醛、酮、亚胺、烯烃等化合物在不同催化体系下发生的不对称加成反应。
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