Synthesis of Cyclic Carbonates from CO_2 and Epoxides Catalyzed by Hexaalkylguanidinium Halides

摘要

Hexaalkylguanidinium halides exhibit an efficient catalytic activity in the synthesis of cyclic carbonates from epoxides and carbon dioxide. By this method cyclic carbonates can be obtained in a high yield and a high selectivity at a low temperature and atmospheric pressure. This procedure is easy for the product isolation and recycling of the catalyst.