高效的电化学能量存储与转换功能材料及其器件近年来受到了人们的广泛关注.层状双金属氢氧化物/石墨烯(LDH/G)复合物就是一类重要的能源材料.它们兼具LDH和石墨烯的优异的物理、化学性能,同时克服了LDH导电性差和石墨烯片易于团聚的问题;在超级电容器和电化学催化分解水等方面具有广泛应用.本文综述了LDH与化学修饰石墨烯(氧化石墨烯,还原氧化石墨烯及其衍生物)的有效复合的方法及其在电化学能量存储与转换领域中的应用,特别是关于基于该类材料的超级电容器及电化学析氧反应催化的研究;对LDH/G复合材料研究领域中的挑战和未来发展方向做了展望.%Functional materials and devices that can efficiently store and convert energies have attracted a great deal of attention in recent years. The composites of layered double hydroxide and graphene (LDH/G) are important energy materials. They have excellent physical and chemical properties of both components. Furthermore, their performances in energy-related systems can be improved by increasing the electrical conductivity of LDHs by blending graphene and partly preventing the aggregation of graphene sheets using LDH nanostructures. Therefore, LDH/G composites can be used in various energy applications, particularly for developing high-performance supercapacitors and efficient electrocatalysts for electrochemical splitting of water. In this review, we summarize the recent advances on the synthesis of LDH/chemically modified graphene (CMG, e.g., graphene oxide, reduced graphene oxide and their derivatives)composites and their application in electrochemical energy storage and conversion. Furthermore, the challenges and future perspectives in this research field are also outlined.
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