Reduced inorganic sulfur in the sediments of the Yellow Sea and East China Sea

摘要

Cold diffusion methods are used to separate and quantify the three reduced inorganic sulfur species into acid volatile sulfide (AVS), pyrite-S and element sulfur (ES) in the sediments of the Yellow and East China Seas. The results show that up to 25.02μmol/g of AVS, 113.1μmol/g of pyrite-S and 44.4μmol/g of ES are observed in the sediments of the Yellow Sea and East China Sea. Pyrite-S is the predominant sulfide mineral in the sediments, while the concentration of AVS is quite low at most stations in the study area. The amounts and reactivity of organic matter are the primary limited factor for the sulfide formation, while an iron limi-tation and a sulfate limitation are not observed in the sediments of the Yellow Sea and East China Sea. The irregular profiles of the three reduced inorganic sulfur species also reflected the comprehensive influence of sediment composition and sedimentation rates.