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Newly Developed Methods for Functionalization of Quaternary Carbons: Decarboxylative Allylation, Benzylation, and Arylation of Nitriles and the Asymmetric Baeyer-Villiger Oxidation of 1,3-Diketones

机译：季碳官能化的新开发方法：腈的脱羧烯丙基化，苯甲酰化和丙烯酸化，以及1,3-二酮的不对称Baeyer-Villiger氧化

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作者
Recio, Antonio, III;
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作者单位

University of Kansas;

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授予单位 University of Kansas;
学科
学位 Ph.D.
年度 2012
页码 209 p.
总页数 209
原文格式 PDF
正文语种 eng
中图分类
关键词
入库时间 2022-08-17 11:56:22

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专利

1. Decarboxylative benzylation and arylation of nitriles [J] . Antonio Recio, Jeffrey D. Heinzman, Jon A. Tunge Chemical Communications . 2012,第1期

机译：腈的脱羧苄基化和芳基化
2. Formation of a quaternary carbon center through the Pd(0)/PhCOOH-catalyzed allylation of cyclic beta-keto esters and 1,3-diketones with alkynes [J] . Patil NT, Yamamoto Y The Journal of Organic Chemistry . 2004,第19期

机译：通过Pd（0）/ PhCOOH催化的炔烃与环状β-酮酯和1,3-二酮的烯丙基化形成季碳中心
3. Palladium-Catalyzed Asymmetric Decarboxylative Allylation of Azlactone Enol Carbonates: Fast Access to Enantioenriched α-Allyl Quaternary Amino Acids [J] . Massimo Serra, Eric Bernardi, Giorgio Marrubini, European journal of organic chemistry . 2019,第4期

机译：钯催化的甲烷酮烯醇碳酸酯的不对称脱羧烯丙基：快速进入对雌激素的α-烯丙基季氨基酸
4. Catalytic Asymmetric Benzylation in the Presence of Planar-Chiral Quaternary Ammonium Salt Using Alkoxide [C] . Wataru Sato, Nobuhiro Kanomata 日本化学会春季年会講演予稿集 . 2018

机译：使用醇盐的平面性 - 手性季铵盐存在催化不对称苄基
5. I. Studies on the organocatalytic formation of quaternary stereocenters. ii. Studies on the claisen rearrangement as a route to quaternary stereocenters. iii. Asymmetric synthesis of aldehydes bearing quaternary carbon centers via the decarboxylative asymmetric allylic alkylation. [D] . Alberch, Eduardo. 2013

机译：I.季铵立体中心的有机催化形成研究。 ii。关于克莱森重排作为四元立体中心路径的研究。 iii。通过脱羧不对称烯丙基烷基化反应不对称合成带有季碳中心的醛。
6. Aza-Riley Oxidation of Ugi-Azide and Ugi-3CR Products toward Vicinal Tricarbonyl Amides: Two-Step MCR-Oxidation Methodology Accessing Functionalized αβ-Diketoamides and αβ-Diketotetrazoles [O] . Christopher Foley, Arthur Shaw, Christopher Hulme -1

机译：Ugi-叠氮化物和Ugi-3CR产品对邻位三羰基酰胺的氮杂-利利氧化反应：两步MCR-氧化方法学可获取功能化的αβ-二酮酰胺和αβ-二酮四唑
7. Palladium-Catalyzed Decarboxylative Aza-Michael Addition-Allylation Reactions between Allyl Carbamates and Activated Olefins. Generation of Quaternary Carbon Adjacent to Secondary Amine Carbon Center [O] . -1

机译：钯催化的脱羧AZA-MICHAEL添加 - 烯丙基氨基甲酸酯和活性烯烃之间的烯丙基化反应。仲胺碳中心相邻的季碳产生
8. Synthesis of Metallacycles by 1,3-Dipolar Cycloaddition Reactions Between Low-Valent Metal Carbonyls and Aryl Nitrile N-Oxides. [R] . Chetcuti, P. A., Walker, J. A., Knobler, C. B., 1988

机译：低价金属羰基化合物与芳基腈N-氧化物之间1,3-偶极环加成反应合成金属环。

Newly Developed Methods for Functionalization of Quaternary Carbons: Decarboxylative Allylation, Benzylation, and Arylation of Nitriles and the Asymmetric Baeyer-Villiger Oxidation of 1,3-Diketones

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