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Copper-based N-heterocyclic carbene complexes for catalytic enantioselective conjugate additions of alkyl-, aryl-, and vinyl-based nucleophiles to form all-carbon quaternary stereogenic centers

机译：铜基N-杂环卡宾配合物，用于烷基，芳基和乙烯基亲核试剂的催化对映选择性共轭加成反应，形成全碳四元立体异构中心

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作者
May, Tricia Lee;
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作者单位

Boston College;

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授予单位 Boston College;
学科
学位 Ph.D.
年度 2011
页码 499 p.
总页数 499
原文格式 PDF
正文语种 eng
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专利

1. All-Carbon Quaternary Stereogenic Centers by Enantioselective Cu-Catalyzed Conjugate Additions Promoted by a Chiral N-Heterocyclic Carbene [J] . M. Kevin Brown, Tricia L. May, Carl A. Baxter, Angewandte Chemie . 2007,第7期

机译：由手性N-杂环卡宾促进对映选择性铜催化共轭加成的全碳四元立体中心
2. All-Carbon Quaternary Stereogenic Centers by Enantioselective Cu-Catalyzed Conjugate Additions Promoted by a Chiral N-Heterocyclic Carbene [J] . M. Kevin Brown, Tricia L. May, Carl A. Baxter, Angewandte Chemie . 2007,第7期

机译：由手性N-杂环卡宾促进对映选择性铜催化共轭加成的全碳四元立体中心
3. Catalytic Asymmetric Alkylations of Ketoimines. Enantioselective Synthesis of N-Substituted Quaternary Carbon Stereogenic Centers by Zr-Catalyzed Additions of Dialkylzinc Reagents to Aryl-, Alkyl-, and Trifluoroalkyl-Substituted Ketoimines [J] . Peng Fu, Marc L. Snapper, Amir H. Hoveyda Journal of the American Chemical Society . 2008,第16期

机译：酮亚胺的催化不对称烷基化。 Zr催化的二烷基锌试剂与芳基，烷基和三氟烷基取代的酮亚胺的Zr催化加成反应，合成N取代的季碳立体异构中心。
4. Copper-catalyzed enantioselective synthesis of tertiary and all-carbon quaternary stereogenic centers through conjugate addition of dialkylzinc reagents to nitroalkenes. [D] . Mampreian, Dawn Marie. 2005

机译：通过将二烷基锌试剂共轭添加到硝基烯烃中，铜催化的叔碳和全碳四元立体异构中心的对映选择性合成。
5. Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five- Six- and Seven-Membered-Ring β-Substituted Cyclic Enones [O] . Tricia L. May, M. Kevin Brown, Amir H. Hoveyda -1

机译：烷基和芳烃铝试剂催化不对称共轭加成五元六元和七元环β-取代的环烯酮的全碳四元立体中心的对映选择性合成
6. A Practical Method for Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers through NHC-Cu-Catalyzed Conjugate Additions of Alkyl- and Arylzinc Reagents to b-Substituted Cyclic Enones [O] . -1

机译：通过NHC-Cu催化的烷基和芳基锌试剂向B取代的环烯酮对所有碳季型立体转发中心进行映射合成全碳季型立体根型综合的实际方法

Copper-based N-heterocyclic carbene complexes for catalytic enantioselective conjugate additions of alkyl-, aryl-, and vinyl-based nucleophiles to form all-carbon quaternary stereogenic centers

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