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Combined Forward Osmosis and Membrane Distillation System for Wastewater Treatment and Reuse.

机译:结合正渗透和膜蒸馏系统进行废水处理和回用。

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摘要

Sustainable solutions for clean, affordable water are becoming increasingly important due to water scarcity problem in different parts of the world. Membrane processes can present an effective approach to address this issue. Recently developed membrane technologies such as forward osmosis (FO) and membrane distillation (MD) have demonstrated many advantages over traditional pressure driven processes. This research evaluated the performance of a combined forward osmosis (FO) and membrane distillation (MD) process for sustainable wastewater treatment and reuse.;Three bench-scale membrane modules were setup in the lab, one forward osmosis (FO) system, one membrane distillation (MD) system and one combined FO-MD system. Water flux was characterized by various operational parameters. FO membrane flux increased with increasing draw solution concentration and temperature. The MD membrane flux was not significantly affected by the draw solution concentration; however, draw solution temperature was the predominant factor. The FO-MD process demonstrated more than 99.9% rejection of combined chemical components when treating ammonium, COD, arsenic and synthetic wastewater. FO alone was not able to reject arsenic efficiently and was supported by MD to achieve more than 99.9% rejection. Secondary effluent from Blue Plains Advanced Wastewater Treatment Plant was used in the FO-MD system, and produced high quality permeate.;The fouling and cleaning behavior of FO and MD membranes were investigated for treating domestic wastewater. Results showed that flux decline caused by organic foulants in wastewater was up to 88% recoverable for FO membrane by cleaning with tap water. For MD membrane, almost no flux recovery was achieved with tap water. Long-term (10 d) tests showed consistent performance of FO membrane by rejecting the contaminants. However, organic foulants reduced the hydrophobicity of the MD membrane, caused wetting problem and allowed contaminants to pass through.;Deteriorating water quality of the Chesapeake Bay has imposed strict regulations of nutrient discharge for the wastewater treatment plants. The liquid extract from solids handling processes, also known as sidestream, can contribute 15 to 30 percent of the total nutrient load. To evaluate the performance of FO-MD system for sidestream treatment, a batch mesophilic anaerobic digester was constructed in the lab. The FO-MD system was able to achieve almost 100% rejection of solids and acetic acid, and more than 98% rejection of NH 3-N from the feed solution. The high rejection of NH 3-N was mainly achieved due to the FO process. The solids in the feed solution contribute to fouling problem in FO. However, 76% flux recovery was achieved by cleaning with tap water. FO membrane also demonstrated excellent performance with 33% more water recovery, when cleaned for 15 min in every 24 h.;Water flux model for the combined FO-MD system was developed and validated with the lab data. The model helped understand the inherent flux balancing mechanism of the combined FO-MD process, and to quantify the fouling effect in the FO process.;Overall, the combined FO-MD process demonstrated high rejection efficiency and low fouling potential; thus can be an effective solution for sidestream treatment to achieve low nutrient discharge limits.
机译:由于世界不同地区的缺水问题,清洁,负担得起的水的可持续解决方案变得越来越重要。膜工艺可以提供解决此问题的有效方法。最近开发的膜技术,例如正渗透(FO)和膜蒸馏(MD),已证明比传统的压力驱动方法具有许多优势。这项研究评估了正向渗透(FO)和膜蒸馏(MD)组合工艺在可持续废水处理和回用方面的性能。;实验室中设置了三个台式规模的膜模块,一个正向渗透(FO)系统,一个膜蒸馏(MD)系统和一个组合式FO-MD系统。水通量通过各种操作参数表征。 FO膜通量随汲取溶液浓度和温度的增加而增加。 MD膜通量不受汲取溶液浓度的显着影响。然而,汲取溶液温度是主要因素。 FO-MD工艺在处理铵盐,化学需氧量,砷和合成废水时表现出99.9%以上的化学成分截留率。单独的FO不能有效地去除砷,而MD则支持其达到99.9%以上的去除率。 FO-MD系统使用了Blue Plains先进废水处理厂的二次废水,并产生了高质量的渗透液。;研究了FO和MD膜的污垢和清洁行为,用于处理生活污水。结果表明,通过用自来水清洗,FO膜可回收废水中有机污垢引起的通量下降高达88%。对于MD膜,用自来水几乎无法实现助熔剂回收。长期(10 d)测试表明,通过排除污染物,FO膜具有一致的性能。然而,有机污垢降低了MD膜的疏水性,引起润湿问题并允许污染物通过。;切萨皮克湾水质恶化已对废水处理厂施加了严格的养分排放规定。来自固体处理过程的液体提取物(也称为侧流)可贡献总养分含量的15%至30%。为了评估FO-MD系统用于侧流处理的性能,在实验室中构建了一个间歇性嗜温厌氧消化池。 FO-MD系统能够实现几乎100%的固体和乙酸截留率,以及98%以上的NH 3-N从进料溶液中截留率。 NH 3-N的高截留率主要是由于FO工艺所致。进料溶液中的固体助长了FO中的结垢问题。但是,用自来水清洗可达到76%的助焊剂回收率。每24小时清洗FO膜一次,每24小时清洗15分钟,FO膜也表现出出色的性能,水回收率提高了33%。该模型有助于理解FO-MD组合工艺固有的通量平衡机制,并量化FO工艺中的结垢效果。总体而言,FO-MD组合工艺具有较高的去除效率和低的结垢潜力。因此可以作为侧流处理的有效解决方案,以实现较低的养分排放极限。

著录项

  • 作者

    Husnain, Taqsim.;

  • 作者单位

    The George Washington University.;

  • 授予单位 The George Washington University.;
  • 学科 Engineering Environmental.;Engineering Civil.
  • 学位 Ph.D.
  • 年度 2014
  • 页码 204 p.
  • 总页数 204
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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