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THE ORIGIN AND EVOLUTION OF THE EARTH'S ATMOSPHERE AND HYDROSPHERE.

机译:地球大气和水体的起源和演变。

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摘要

The origin and evolution of the earth's atmosphere has been a much studied subject ever since the early nineteen hundreds. This problem has been investigated from various perspectives, such as geological, biological and physical.; Because of the uncertainty regarding the processes which led to the formation of life, the biological studies have been forced to include certain fundamental assumptions. These assumptions are presented in the discussion section.; The physical studies, on the other hand, have made fewer assumptions and have led to a greater understanding of the origin of the atmosphere. These studies have suggested that the processes by which the earth was formed were different from that of the other planets. One consequence of this difference is that the earth may have lost its primary atmosphere fairly early in it's history. Consequently, the present atmosphere is the result of outgassing from the interior of the earth. It has also been shown that the outgassing occurred over all geological time, not just in a short period.; The composition of the outgassed fluid has been a point of serious debate. In this work, a model developed by Melton and Giardini (1983) has been used. In this model, the fluid inclusions in diamonds have been taken as original samples of the outgassed fluids. The model uses first order kinetics of the degassing processes of H(,2), CH(,4), N(,2), CO and Ar, and zero order kinetics for the degassing processes of H(,2)O and CO(,2).; In this work, samples with compositions similar to the fluid included in diamonds were exposed to electric discharge, UV radiation and gamma radiation to formulate the equilibrium composition of the earth's atmosphere. The change of the composition was slight after the samples were exposed to the various high energy sources. Therefore, I postulate that the composition in the inclusion was very close to the equilibrium condition and use these values, with slight corrections, to tabulate the earth's early atmosphere.; Small amounts of organic and inorganic compounds were formed in the samples by the radiation. These are a possible source of fundamental materials necessary for the formation of living systems.; The Melton/Giardini model was used to calculate the composition and pressure of primitive atmosphere of the earth as a function of time, beginning 4.5 b.y. ago. Since light gases such as H(,2) and He escape from the earth, and other degassed material undergoes numerous chemical and physical reactions, the earth's atmosphere was quite different from the predicted composition using the uncorrected Melton/Giardini model.
机译:自一千九百年代初期以来,地球大气的起源和演变一直是一个受到广泛研究的主题。已经从各种角度研究了这个问题,例如地质,生物和物理。由于导致生命形成过程的不确定性,生物学研究被迫包括某些基本假设。这些假设在讨论部分中介绍。另一方面,物理研究做出的假设更少,导致人们对大气的起源有了更多的了解。这些研究表明,地球形成的过程不同于其他行星。这种差异的结果是,地球可能在其历史的早期就失去了主要大气层。因此,目前的大气是从地球内部释放出气体的结果。还表明,放气不仅发生在短时间内,而且发生在整个地质时期。脱气流体的组成一直是一个严肃的争论点。在这项工作中,使用了由Melton和Giardini(1983)开发的模型。在此模型中,钻石中的流体夹杂物已被用作脱气流体的原始样品。该模型使用H(,2),CH(,4),N(,2),CO和Ar的脱气过程的一阶动力学以及H(,2)O和CO的脱气过程的零阶动力学(,2).;在这项工作中,将具有与钻石中所含流体相似的成分的样品暴露于放电,紫外线辐射和伽马辐射下,以制定地球大气的平衡组成。在样品暴露于各种高能量源之后,组成的变化很小。因此,我假设夹杂物中的成分非常接近平衡条件,并使用这些值(稍作修正)将地球的早期大气制成表格。通过辐射在样品中形成少量的有机和无机化合物。这些可能是生命系统形成所必需的基础材料。梅尔顿/贾尔迪尼模型被用来计算地球原始大气层的组成和压力随时间的变化,从公元前4.5年开始。前。由于诸如H(,2)和He之类的轻气体从地球逸出,并且其他脱气材料经历了许多化学和物理反应,因此,使用未经校正的Melton / Giardini模型,地球大气与预测的成分完全不同。

著录项

  • 作者单位

    University of Georgia.;

  • 授予单位 University of Georgia.;
  • 学科 Chemistry General.
  • 学位 Ph.D.
  • 年度 1984
  • 页码 169 p.
  • 总页数 169
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

  • 入库时间 2022-08-17 11:51:12

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