Chemical structure and kinetic modeling of 1,2-dichloroethane/methane fuel-rich flames.

摘要

The chemical structure of atmospheric, premixed, one-dimensional, laminar, fuel-rich flames of 1,2-dichloroethane (1,2-DCE)/CH;The flame structure of 1,2-DCE fuel-rich flames exhibit considerable complexity, as evidenced by the abundance of the species observed. A number of important flame species have been identified and quantified for the first time in the flames of 1,2-DCE. In addition to those for the reactants, the mole fraction profiles of CO, CO;In another stoichiometric, pure 1,2-DCE flame, a significant level of highly substituted chlorinated hydrocarbons, such as CCl;A detailed chemical kinetic mechanism for the combustion of 1,2-DCE/CH