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Reactive flow in vuggy carbonates: Methods and models applied to matrix acidizing of carbonates.

机译:多孔碳酸盐中的反应流:应用于碳酸盐基质酸化的方法和模型。

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摘要

Carbonates invariably have small (micron) to large (centimeter) scale heterogeneities in flow properties that may cause the effects of injected acids to differ greatly from what is predicted by a model based on a homogenous formation. To the best of our knowledge, there are neither theoretical nor experimental studies on the effect of large scale heterogeneities (vugs) on matrix acidizing. The abundance of carbonate reservoirs (60% of the world's oil reserves) and the lack of a detailed study on the effect of multi-scale heterogeneities in carbonate acidizing are the main motivations behind this study.;In this work, we first present a methodology to characterize the carbonate cores prior to the core-flood acidizing experiments. Our approach consists of characterization of the fine-scale (millimeter) heterogeneities using computerized tomography (CT) and geostatistics, and the larger-scale (millimeter to centimeter) heterogeneities using connected component labeling algorithm and numerical simulation.;In order to understand the connectivity of vugs and thus their contribution to flow, a well-known 2D visualization algorithm, connected component labeling (CCL), was implemented in 3D domain. Another tool used in this study to understand the connectivity of the vugs and its effect on fluid flow is numerical simulation. A 3D finite difference numerical model is developed based on Darcy-Brinkman formulation (DBF). Using the developed simulator a flow-based inversion approach is implemented to understand the connectivity of the vugs in the samples studied.;After multi-scale characterization of the cores, acid core-flood experiments are conducted. Cores measuring four inches in diameter by twenty inches in length are used to decrease the geometry effects on the wormhole path. The post acid injection porosity distribution and wormhole paths are visualized after the experiments.;The experimental results demonstrate that acid follows not only the high permeability paths but also the spatially correlated ones. While the connectivity between the vugs, total amount of vuggy pore space and size of the cores are the predominant factors, spatial correlation of the petro-physical properties has less pronounced effect on wormhole propagation in acidiziation of carbonates.;The fact that acid channeled through the vugular cores, following the path of the vug system, was underlined with computerized tomography scans of the cores before and after acid injection. This observation proposes that local pressure drops created by vugs are more dominant in determining the wormhole flow path than the chemical reactions occurring at the pore level. Following this idea, we present a modeling study in order to understand flow in porous media in the presence of vugs. Use of coupled Darcy and Stokes flow principles, known as Darcy-Brinkman formulation (DBF), underpins the proposed approach. Several synthetic simulation scenarios are created to study the effect of vugs on flow and transport.;The results demonstrate that total injection volume to breakthrough is affected by spatial distribution, amount and connectivity of vuggy pore space. An interesting finding is that although the presence and amount of vugs does not change the effective permeability of the formation, it could highly effect fluid diversion. We think this is a very important observation for designing of multi layer stimulation.
机译:碳酸盐在流动性质上始终具有小(微米)到大(厘米)规模的异质性,这可能导致注入的酸的影响与基于均质地层的模型所预测的有很大不同。据我们所知,对于大规模异质性(孔洞)对基质酸化的影响,既没有理论研究也没有实验研究。碳酸盐岩储层的丰富(占世界石油储量的60%)以及缺乏对多尺度非均质性对碳酸盐酸化的影响的详细研究是这项研究的主要动机。在这项工作中,我们首先提出一种方法在岩心驱替酸化实验之前表征碳酸盐岩心。我们的方法包括使用计算机断层扫描(CT)和地统计学来表征精细尺度(毫米)的异质性,以及使用连接组件标记算法和数值模拟来表征较大尺度(毫米至厘米)的异质性;为了理解连通性由于存在大量的微孔,因此对微孔的贡献很大,在3D域中实现了一种众所周知的2D可视化算法,即连接组件标记(CCL)。这项研究中用来了解孔洞的连通性及其对流体流动的影响的另一个工具是数值模拟。基于Darcy-Brinkman公式(DBF)开发了3D有限差分数值模型。使用开发的模拟器,采用基于流的反演方法来理解所研究样品中孔洞的连通性。在对岩心进行多尺度表征之后,进行了酸性岩心驱油实验。使用直径为4英寸乘以20英寸长的岩心来减少对虫洞路径的几何影响。实验后可视化了注酸后的孔隙度分布和虫洞路径。实验结果表明,酸不仅遵循高渗透率路径,而且遵循空间相关的路径。尽管孔洞之间的连通性,孔洞孔的总量和岩心的大小是主要因素,但在碳酸盐化过程中,岩石物理性质的空间相关性对虫洞传播的影响较小。在注酸之前和之后,通过对核的计算机断层扫描来强调沿着核系统的路径的核芯。该观察结果表明,由孔洞产生的局部压降在确定虫孔流动路径方面比在孔水平处发生的化学反应更占优势。遵循这个想法,我们提出了一个模型研究,以了解在存在孔洞的情况下多孔介质中的流动。 Darcy-Brinkman公式(DBF)被称为Darcy和Stokes耦合流动原理的使用,为所提出的方法奠定了基础。创建了几种综合模拟方案来研究孔洞对流动和运输的影响。结果表明,通孔的总注入量受孔洞空间的空间分布,数量和连通性的影响。一个有趣的发现是,尽管孔洞的存在和数量不会改变地层的有效渗透率,但它可能会极大地影响流体分流。我们认为这对于设计多层刺激非常重要。

著录项

  • 作者

    Izgec, Omer.;

  • 作者单位

    Texas A&M University.;

  • 授予单位 Texas A&M University.;
  • 学科 Engineering Petroleum.
  • 学位 Ph.D.
  • 年度 2009
  • 页码 174 p.
  • 总页数 174
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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