The development of surface NMR-electrochemistry: A new in situ analytical probe to examine electrochemical interfaces.

摘要

lectrode potential-dependent NMR measurements of a ;My thesis discusses the challenges of developing the surface NMR-electrochemistry method, as well as the solutions obtained to overcome them. Digitizing overload, RF penetration, vibrations, and the interfacing of electrochemistry to NMR are examined. Several second-generation probes, as well as computer simulations, were designed to expand the capabilities of this method. Analyses of a broad range of NMR spectra and cyclic voltammetry profiles of methanol-derived