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Microwave processing of ceramics and ceramic composites using a single-mode microwave cavity.

机译:使用单模微波腔对陶瓷和陶瓷复合材料进行微波处理。

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摘要

This research seeks (i) to use a single-mode microwave cavity to process ceramics and ceramic based composites, (ii) to study the conditions or parameters needed to successfully apply the microwaves to processing of materials, and (iii) to study the interactions between materials and microwaves.; In sintering studies, alumina ceramics and alumina matrix 10wt% zirconia composites were microwave-heated between 1500{dollar}spcirc{dollar}C and 1600{dollar}spcirc{dollar}C giving a density of about 96% up to nearly 100% of theoretical without 'thermal runaway' or cracking. The density, hardness, and toughness for individually- and batch-processed specimens were relatively uniform with respect to the cavity mode and specimens' location inside the insulation called 'casket' during microwave heating. For example, the mean and standard deviation of the hardness was 16.19 GPa {dollar}pm{dollar} 0.58 GPa for a total of 24 alumina specimens microwave-heated in batches of 6 specimens each. This corresponds to a coefficient of variation of only 0.036.; Microwave power was successfully utilized to burn out organic binder from ceramic powder compacts without cracking the specimens and without using any insulation material to enclose the specimens. The extent of binder burn-out significantly depended on material composition due to the dielectric properties of each material. For example, Al{dollar}sb2{dollar}O{dollar}sb3{dollar}/10wt% SiC burned out the binder more successfully than either monolithic alumina or alumina containing 10wt% zirconia.; In a joining study, ceramic materials and glass ceramics were successfully joined using a spin-on material interlayer under ambient or low externally applied pressures. Notches of submillimeter dimension were made in the specimens prior to joining. During the joining process the notch dimensions changed by no more than a few percent.; In addition, this study revealed that compared to conventional heating, microwave heating has remarkable effects in crack healing. For alumina specimens with initial Vickers cracks about 350{dollar}mu{dollar}m long, the cracks were nearly completely healed by microwave heating at 1742K, while conventional heating healed the identical cracks by only about 40% to 50% of the initial crack length.; In microwave hybrid heating utilizing a casket, the casket plays an important role. The measured steady-state inner wall casket temperature, T{dollar}sb{lcub}rm i{rcub}{dollar}, varied from about 1100{dollar}spcirc{dollar}C to 1500{dollar}spcirc{dollar}C depending on the casket geometry at 600 Watts input power. In addition, for a microwave input power of 200 Watts to 700 Watts, T{dollar}sb{lcub}rm i{rcub}{dollar} ranged from 740{dollar}spcirc{dollar}C to 1574{dollar}spcirc{dollar}C depending on a combination of casket geometry and microwave power. Based on the experimental data, a simple model equation was developed to describe T{dollar}sb{lcub}rm i{rcub}{dollar} in terms of the casket geometry and the microwave power level. A least-squares fitting indicated that the model equation well described the experimental data obtained in this study. The R{dollar}sp2{dollar}, coefficient of determination value was 0.954 for all 144 data used for fitting without grouping the data.
机译:这项研究旨在(i)使用单模微波腔来处理陶瓷和陶瓷基复合材料,(ii)研究成功将微波应用于材料处理所需的条件或参数,以及(iii)研究相互作用在材料和微波之间。在烧结研究中,将氧化铝陶瓷和氧化铝基10wt%的氧化锆复合材料在1500spC和1600spC之间进行微波加热,密度约为96%,最高可达100%。理论上没有“热失控”或开裂。相对于模腔模式和微波加热期间样品在绝缘体内部的位置(称为“棺材”),单个和批处理样品的密度,硬度和韧性相对均匀。例如,对于总共24个氧化铝试样(每组6个试样进行微波加热),硬度的平均和标准偏差为16.19 GPa {pm} pm {dollar} 0.58 GPa。这对应于仅0.036的变异系数。微波功率已成功用于从陶瓷粉末压块中烧掉有机粘合剂,而不会使样品破裂,也无需使用任何绝缘材料将样品包围起来。由于每种材料的介电特性,粘合剂的烧尽程度很大程度上取决于材料组成。例如,Al {dollar} sb2 {dollar} O {dollar} sb3 {dollar} / 10wt%SiC比整体式氧化铝或含10wt%氧化锆的氧化铝更成功地烧掉了粘合剂。在一项连接研究中,使用旋涂材料夹层在环境压力或外部施加的低压力下成功地连接了陶瓷材料和玻璃陶瓷。在连接之前,在样品中制作了亚毫米尺寸的缺口。在连接过程中,槽口尺寸变化不超过百分之几。此外,这项研究表明,与常规加热相比,微波加热在裂纹愈合方面具有显着效果。对于初始维氏裂纹长约350 {μm}μm{dollar} m的氧化铝试样,在1742K的微波加热下,裂纹几乎被完全治愈,而常规加热仅使相同的裂纹恢复了原始裂纹的40%至50%。长度。;在利用棺材的微波混合加热中,棺材起着重要的作用。测得的稳态内壁棺材温度T {dollar} sb {lcub} rm i {rcub} {dollar}的范围从1100 {dollar} spcirc {dollar} C到1500 {dollar} spcirc {dollar} C不等在600瓦输入功率下的棺材几何形状上。此外,对于200瓦至700瓦的微波输入功率,T {dollar} sb {lcub} rm i {rcub} {dollar}的范围从740 {dollar} spcirc {dollar} C到1574 {dollar} spcirc {dollar } C,取决于棺材的几何形状和微波功率。根据实验数据,开发了一个简单的模型方程,用棺材几何形状和微波功率水平描述了T {dollar} sb {lcub} rm i {rcub} {dollar}。最小二乘拟合表明模型方程很好地描述了本研究中获得的实验数据。对于用于拟合而不对数据进行分组的所有144个数据,R {dol2} sp2 {dollar}的确定系数值为0.954。

著录项

  • 作者

    Lee, Ki-Yong.;

  • 作者单位

    Michigan State University.;

  • 授予单位 Michigan State University.;
  • 学科 Engineering Materials Science.; Engineering Mechanical.; Applied Mechanics.
  • 学位 Ph.D.
  • 年度 1998
  • 页码 343 p.
  • 总页数 343
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 工程材料学;机械、仪表工业;应用力学;
  • 关键词

  • 入库时间 2022-08-17 11:48:40

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