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Experimental and modeling studies on a catalytic packed bed membrane reactor.

机译:催化填充床膜反应器的实验和模型研究。

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摘要

In the present work, the effects of operating conditions in a catalytic packed bed membrane reactor were investigated with the reactant gases H 2 and CO flowing through the membrane tube, and an inert gas N 2 flowing on the outside. The reaction under study was methanol synthesis with BASF catalyst, and a gamma-alumina membrane with a nominal pore size of 40 A was used.;Preliminary experiments were carried out in the membrane reactor without any catalyst inside membrane to characterize it in terms of its flux, permeance, and selectivity of H2 over CO. Experiments were carried out in the packed bed membrane reactor to study the effects of these conditions on the conversion. A mathematical model was developed for the reactor. Experiments with similar operating conditions were then carried out in the packed bed tubular reactor. Finally, results of comparison of the two reactors were discussed with recommendations for further studies.
机译:在目前的工作中,研究了反应填充床膜反应器中操作条件的影响,其中反应气体H 2和CO流经膜管,惰性气体N 2在外部流过。研究的反应是使用BASF催化剂合成甲醇,并使用标称孔径为40 A的γ-氧化铝膜。;在膜反应器中进行了初步实验,膜内没有任何催化剂,以对其进行表征H 2相对于CO的通量,渗透率和选择性。在填充床膜反应器中进行了实验,研究了这些条件对转化率的影响。为反应堆开发了数学模型。然后在填充床管式反应器中进行了具有类似操作条件的实验。最后,讨论了两个反应堆的比较结果,并提出了进一步研究的建议。

著录项

  • 作者

    Deshpande, Ashutosh G.;

  • 作者单位

    West Virginia University.;

  • 授予单位 West Virginia University.;
  • 学科 Engineering Chemical.
  • 学位 M.S.
  • 年度 1998
  • 页码 116 p.
  • 总页数 116
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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