Instrumentation for time-resolved dynamic and static dichroic measurements of polymers with a near-IR acoustooptic tunable filter.

摘要

The optical measurement of the orientational response of chemical functional groups of a polymer as it is subjected to conventional dynamic mechanical analysis can give insight into the rheological behavior of the polymer while under repetitive strain based on the chemical structure. Instrumentation used in the mid infrared has included the use of grating monochromators and interferometers. The use of a multiply modulated optical signal has decreased the level of noise to observe the small amplitude changes (typically >10-3 absorbance units) associated with the repetitive oscillatory strain. The use of digital signal processing to replace phase sensitive detection for demodulation of the optical signal has greatly reduced the spectral collection time. In addition, multiplexing gained with the use of step-scan interferometry in making time resolved measurements has aided in making the procedure more practical. However, instrumental complexity and expense are drawbacks. By incorporating the high throughput, polarized tuned beam, and rapid wavelength switching capability of an acousto-optic tunable filter (AOTF), a dynamic instrument with integrated centralized control by a single microprocessor has been built. it operates in the near infrared with a rapid dynamic data collection time and requires the use of only a single modulation in the form of the sample oscillatory strain. The near infrared permits thicker samples to reduce sample preparation tune or allows polymers to be tested without pretreatment. The use of Fourier based digital filtering improves the signal to noise ratio of the dynamic differential spectra. The instrument is cost effective and rugged in comparison to step-scan interferometers yet has a rapid data collection rate allowing use in a routine industrial setting. Information from these measurements can aid in determining the rheological properties necessary for the end use functionality of a polymer. Additionally, AOTF instrumentation can be used for static dichroic measurements of polymers for routine testing. An example of this is the routine measurement of the dichroic ratio of a natural protein biopolymer, wheat gluten (film), as an indication of the gluten strength. This type of measurement has the potential to be useful in the improvement of wheat varieties and in the indication of wheat quality for end use.