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Electronic, Magnetic, and Thermal properties of lead(A)chromium oxide (A = potassium or lanthanum).

机译:氧化铅(A)(A =钾或镧)的电子,磁和热性能。

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摘要

Lead chromium oxide is a photoconductive dielectric material that has great potential of being used as a room temperature photodetector. In this research, we made ceramic pellets of this compound as well as potassium doped compound Pb2-xKxCrO 5, where x=0, 0.05, 0.125. We also investigate the properties of the lanthanum doped sample whose chemical formula is Pb1.85La 0.15CrO5. The electronic, magnetic and thermal properties of these materials have been studied. Magnetization measurements of the Pb 2CrO5 sample indicate a transition at about 310 K, while for the lanthanum doped sample the transition temperature is at about 295 K indicating a paramagnetic behavior. However, the potassium doped samples are showing the transition from paramagnetic state to diamagnetic state at different temperatures for different amounts of potassium atoms present in the sample. We have studied resistivity as a function of temperature in different gas environments from 300 K to 900 K. The resistivity measurement of the parent sample indicates a conducting to insulating transition at about 300 K and upon increasing the temperature further, above 450 K the sample becomes an ionic conductor. As temperature increases a decrease in resistance is observed in the lanthanum/potassium doped samples. Using Differential Scanning Calorimetry experiment an endothermic peak is observed for the Pb2CrO 5 and lanthanum/potassium doped samples at about 285 K.
机译:氧化铬铅是一种有很大潜力被用作室温光电探测器的光电导材料。在这项研究中,我们制得了该化合物以及掺钾化合物Pb2-xKxCrO 5的陶瓷颗粒,其中x = 0、0.05、0.125。我们还研究了化学式为Pb1.85La 0.15CrO5的镧掺杂样品的性能。已经研究了这些材料的电子,磁性和热学性质。 Pb 2CrO5样品的磁化测量表明在约310 K处发生了转变,而对于镧掺杂的样品,转变温度在295 K处表明了顺磁行为。然而,对于样品中存在的不同数量的钾原子,钾掺杂样品在不同温度下显示出从顺磁态到抗磁态的转变。我们已经研究了在300 K至900 K的不同气体环境中电阻率与温度的关系。对母体样品的电阻率测量表明,在大约300 K时,导体会发生绝缘转变,并且在温度进一步升高时,超过450 K时,样品变为离子导体。随着温度升高,在掺杂镧/钾的样品中观察到电阻降低。使用差示扫描量热法实验,在约285 K处观察到Pb2CrO 5和镧/钾掺杂样品的吸热峰。

著录项

  • 作者

    Indovski, Biljana.;

  • 作者单位

    Brock University (Canada).;

  • 授予单位 Brock University (Canada).;
  • 学科 Physics High Temperature.;Physics Condensed Matter.
  • 学位 M.Sc.
  • 年度 2011
  • 页码 65 p.
  • 总页数 65
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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