首页> 外文学位 >The synthesis and characterization of energetic materials from sodium azide.
【24h】

The synthesis and characterization of energetic materials from sodium azide.

机译:叠氮化钠含能材料的合成与表征。

获取原文
获取原文并翻译 | 示例

摘要

A tetrazole is a 5-membered ring containing 4 nitrogens and 1 carbon. Due to its energetic potential and structural similarity to carboxylic acids, this ring system has a wide number of applications. In this thesis, a new and safe sustainable process to produce tetrazoles was designed that acheived high yields under mild conditions. Also, a technique was developed to form a trityl-protected tetrazole in situ. The rest of this work involved the exploitation of the energetic potential of tetrazoles. This moiety was successfully applied in polymers, ionic liquids, foams, and gels. The overall results from these experiments illustrate the fact that tetrazoles have the potential to serve as a stable alternative to the troublesome azido group common in many energetic materials. Due to these applications, the tetrazole moiety is a very important entity.
机译:四唑是含有4个氮和1个碳的5元环。由于其高能势和与羧酸的结构相似性,该环体系具有广泛的应用。本文设计了一种新的,安全的,可持续的生产四唑类的方法,该方法在温和条件下可实现高产。而且,开发了一种原位形成三苯甲基保护的四唑的技术。这项工作的其余部分涉及对四唑的能量潜力的开发。该部分已成功应用于聚合物,离子液体,泡沫和凝胶中。这些实验的总体结果说明了一个事实,即四唑有可能作为许多高能材料中常见的麻烦叠氮基的稳定替代品。由于这些应用,四唑部分是非常重要的实体。

著录项

  • 作者

    Aronson, Josh.;

  • 作者单位

    Georgia Institute of Technology.;

  • 授予单位 Georgia Institute of Technology.;
  • 学科 Chemistry Organic.
  • 学位 Ph.D.
  • 年度 2004
  • 页码 162 p.
  • 总页数 162
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号