Collinear fast-beam laser spectroscopy is a method of studying atomic and ionic hyperfine structure where a particle beam and a laser beam are superposed along the same line. Such a facility exists at ISAC, TRIUMF, Vancouver, BC, and was designed especially for polarising radioactive beams of alkali metals.; In order to produce polarised fluorine for the use in NMR, the hyperfine structure of the 3s 4P 5/2 and 3p 4D 7/2 states has to be known. The hyperfine coefficients for those two levels are measured for the first time to be A = 2645.6(6) MHz and A = 1565.6(4)MHz respectively. The 3p 4D5/2 state is also studied to measure the metastable atom fraction and its hyperfine constant is measured to be A = 1148(5)MHz.; A study of lanthanum ions is also carried out. Spectra for the 6 s2 1S0 to 5 d6p Do13 transition are measured with stable 139La to evaluate the sensitivity of the equipment and with radioactive 139La for preliminary commissioning of the isotope shift study.
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