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#ew Iron Oxide positive Active material For Lithium Secondary Batteries#K.Amine; H.Yasu

机译:#ew锂二次电池氧化铁正极活性材料亚苏

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ersibly lithium in the tunnels. This material exhibit three voltage plateaus at 2.3, 1.5 and 0.7 V and has an over all discharge capacity of 1100 mAh/g. When cycling in the 2-V region, the material exhibits high capacity of 275 mAh/g and very good cyclic reversibility. X-ray photoelectron spectroscopy of the discharged material showed that iron is reduced to the divalent state, and the lithium incorporated in the tunnels is purely ionic. This result explains the good reversibility of this electrode material. When of two conducting polymers, polyaniline and polypyrrole, could result in much improved physical properties with respect to their applciations in pH electrodes and conducting paints/coatings. However, the composite has time dependant propertie that ma
机译:隧道中的锂。该材料在2.3、1.5和0.7 V时表现出三个电压平稳状态,并且总放电容量为1100 mAh / g。当在2-V区域循环时,该材料表现出275 mAh / g的高容量和非常好的循环可逆性。放电材料的X射线光电子能谱表明,铁被还原为二价态,并且结合在隧道中的锂是纯离子的。该结果说明了该电极材料的良好可逆性。当使用两种导电聚合物时,聚苯胺和聚吡咯在其在pH电极和导电漆/涂料中的应用方面可能会导致物理性能大大改善。但是,复合材料具有随时间变化的特性,即

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