Two tin-graphite composite electrodes were evaluated for their use as high capacity anodes in recahargeable lithium ion cells. The initial charge capacitie of these two electrodes were 520 mAh/g, respectively. Cyclic voltammetry and charge-discharge cycling studies point to the alloy formation reaction between tin and lithium being the main contributing factor ot the increased capacity. The capacity ofthese electrodes decreases with cycling but maintains considerably higher capacity than graphite electrode with same number of cycles. The development of optimized tin-graphite composite electrodes with much higher capacity than graphite electrodes looks promising.
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机译:评价了两个锡-石墨复合电极在可再充电锂离子电池中作为高容量阳极的用途。这两个电极的初始充电容量分别为520 mAh / g。循环伏安法和充放电循环研究表明,锡和锂之间的合金形成反应是增加容量的主要因素。这些电极的容量随着循环而减小,但是与相同次数的石墨电极相比,保持了更高的容量。具有比石墨电极高得多的容量的优化的锡-石墨复合电极的开发看起来很有希望。
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