Electrochemical Performances of a Thin Film Type SOFC on a Porous lYIicrotubular Support

摘要

This report summarizes electrochemical performances of a thin film type SOFC prepared on a porous microtubular support. The sample was prepared via the co-sintering of YSZ electrolyte and NiO-YSZ anode bilayers on a porous microtubular YSZ support, and then an LSCF-GDC cathode layer was also prepared on the electrolyte film. Evaluations were conducted using impedance analyzer and potentio/galvanostat under a humidified hydrogen flow. Film thickness of the anode layer was controlled by the composition of the anode coating suspension and the coating conditions (coating number and coating speed etc.). Impedance analyses showed that with increasing operation temperature, semicircle at higher frequency region became small, while semi-circle at lower frequency region weakly depended on the temperature. Electrode activation energy was calculated to be approximately 80 kJ/mol using Arrhenius plot on the semi-circle at higher frequency region.