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Corrosion Resistance of TiN Imitation Gold Decoration Coatings on Golden-Pen Components

机译:TiN仿金装饰涂料对金笔零件的耐蚀性

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Experiments were carried out with different process parameters to investigate the effects of used parameters on corrosion resistance of TiN coatings obtained. In experiments, TiN imitation gold decoration coatings were prepared on 1Cr13 pen-point and brass chromium plating pen-coil by multi-arc ion plating method. The phase composition of TiN coatings was measured by x-ray diffraction. The corrosion resistance of TiN coatings was tested by salt-mist and artificial-sweat experiments. The relationship between corrosion resistance of coatings and process parameters were analyzed. Therefore, the optimum process parameters were achieved suitable for plating coatings on substrates of 1Cr13 pen-point and brass chromium plating pen-coil with good imitation gold. Imitation gold plating layers obtained have good gloss, corrosion resistance, high hardness, wear resistance, and easy to maintain. The results showed that the corrosion resistance of coatings is more easily influenced by changes of P_(N2) and V_(bom) than that of matrix-bias voltage. The TiN coatings are of resistant to corrosion no matter they are in single or multi phase structure. The optimum parameters of achieving good corrosion resistance of TiN coatings are P_(N2) = 0.48Pa, V_(bom)=400V, bias=-20V. Under the optimum conditions, the obtained surface corrosion resistance state of the coatings can reach at least eight grades, even above ten grades.
机译:用不同的工艺参数进行了实验,以研究所用参数对所得TiN涂层耐蚀性的影响。实验中,采用多弧离子镀法在1Cr13笔尖和黄铜镀铬笔圈上制备了TiN仿金装饰涂料。 TiN涂层的相组成通过X射线衍射测量。 TiN涂层的耐腐蚀性通过盐雾试验和人工汗液试验进行了测试。分析了涂层的耐蚀性与工艺参数之间的关系。因此,获得了最佳工艺参数,适用于在1Cr13笔尖的基底和具有良好仿金的黄铜铬镀层笔形线圈上进行镀层。所得的仿金镀层具有良好的光泽度,耐腐蚀性,高硬度,耐磨性,并且易于维护。结果表明,与基体偏压相比,P_(N2)和V_(bom)的变化更容易影响涂层的耐蚀性。无论是单相还是多相结构,TiN涂层均具有耐腐蚀性能。获得良好的TiN涂层耐腐蚀性的最佳参数是P_(N2)= 0.48Pa,V_(bom)= 400V,bias = -20V。在最佳条件下,所获得的涂层表面抗腐蚀状态至少可以达到八个等级,甚至十个等级以上。

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