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Phosphotungstic acid/semi-coke catalysts for oxidative desulfurization of diesel fuel

机译:磷钨酸/半焦催化剂用于柴油机的氧化脱硫

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摘要

This work presents the results obtained in the development of phosphotungstic acid/semi-coke catalysts in the oxidative desulfurization (ODS) process of diesel oil using hydrogen peroxide as the oxidizing agent. Phosphotungstic acid /semi-coke (60wt%) prepared by impregnation. These catalysts were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM), The effect of the amount of catalyst used , on the efficiency of desulfurization was investigated. In addtion. the diesel after oxidation and extraction was analyzed by GC-FPD for sulfur content. The chromatograph shows that virtually all the sulfur containing compounds in diesel were removed.
机译:这项工作介绍了在使用过氧化氢作为氧化剂的柴油氧化脱硫(ODS)过程中开发磷钨酸/半焦催化剂的结果。通过浸渍制备磷钨酸/半焦(60wt%)。通过X射线衍射(XRD)和扫描电子显微镜(SEM)对这些催化剂进行了表征,研究了催化剂用量对脱硫效率的影响。另外。氧化萃取后的柴油通过GC-FPD分析硫含量。色谱图表明,柴油中几乎所有的含硫化合物都被去除了。

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  • 来源
  • 会议地点 Qingdao(CN)
  • 作者单位

    College of Chemistry and Chemical Engineering, Ocean University of China, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, P.R.China ,Qingdao 266100;

    College of Chemistry and Chemical Engineering, Ocean University of China, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, P.R.China ,Qingdao 266100;

    College of Chemistry and Chemical Engineering, Ocean University of China, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, P.R.China ,Qingdao 266100;

  • 会议组织
  • 原文格式 PDF
  • 正文语种
  • 中图分类 工程材料学 ;
  • 关键词

    Solid Acid Catalysts; Desulfurization; Oxidation; Semi-coke;

    机译:固体酸催化剂;脱硫氧化;半焦;

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