Synthesis of β-Sialon/Ti(C,N) Composites Using Low and Middle Grade Bauxite and Ilmenite by Carbothermal Reduction-Nitridation

摘要

β-Sialon/Ti(C,N) composites were prepared using low and middle grade bauxite and ilmenite as raw material,while coke as reducing agent in high purity nitrogen atmosphere through carbothermal reduction-nitridation(CRN).The main phases of low and middle grade bauxite are kaolinire(Al2O3·2SiO2·2H2O) and (Al2O3·H2O)2 and ilmenite mainly contain ilmenite(FeTiO3) and rutile(TiO2).The reaction products of bauxite are the β-Sialon(Z=3,Si3Al3O3N5) while those of ilmenite are TiC and Fe.The results showed that the main phases are β-Sialon,Ti(C,N),Al2O3 and Fe when the reaction temperature is at 1400℃ holding for 4 hours (10wt％ ilmenite and 90wt％ bauxite as raw material).However,β-Sialon decomposes into 21R at 1450℃ and into 15R and AlN at 1500℃.So 1400℃ is selected as the proper temperature to synthesize β-Sialon/Ti(C,N) composites.At 1400℃,the β-Sialon crystals with the largest quantity grow well and show long column in shape.With the increase of the reaction temperature β-Sialon begins to decompose,the β-Sialon crystals change to short columnar,with the number decreasing quickly.