Supramolecular Structures with Metal-Oxalate Framework forMolecular Electronic Materials based on Gyroids

摘要

[MnCr(oxalate)]-complexes form network structures from 1D to 3D through alternatearrangement of Mn2+ and Cr3+ in the crystal.Especially,two-dimensional honeycombstructures exhibit ferromagnetic transitions at around 5 K and can incorporate variety ofcation structures between the layers such as organic conductors exhibiting metallicconductivity1 and chiral cations inducing chiral magnetism.In the present study,weintroduced supramolecular cation structures in the network of [MnCr(oxalate)]-to developmultifunctional materials based on the dynamic feature of supramolecular cations andferromagnetic properties of [MnCr(oxalate)]-.