Development of N-doped Carbon Incarcerated CopperNanoparticle Catalysts for Aerobic Oxidation of AliphaticAlcohols and Its Application to Continuous-flow Systems

摘要

Oxidation reactions of alcohols to aldehydes are one of the powerful tools inorganic synthesis.In particular,a combination of Cu and an N-oxyl radical is knownas a good homogeneous co-catalyst system for oxidation of aliphatic alcohols,whichare generally more difficult substrates than aromatic alcohols.However,oxidation ofaliphatic alcohols is still difficult in heterogeneous systems.