Nickel(Ⅱ)–Catalyzed Reaction of Aromatic Amides with Bicyclic Alkenes through Carbon–Hydrogen and Carbon–Nitrogen Bond Cleavage

摘要

Fluorenone derivatives are naturally occurring active molecules. Various types of hydrofluorenone derivatives were also isolated from natural sources. Because of their potential bioactivities, the construction of the core fluorenone and hydrofluorenone are attracting considerable attention. In fact, many groups reported a synthetic method of hydrofluorenones using catalytic systems of noble metals.