Organic-Inorganic Hybrids Based on Keggin-Type Trivacant Lacunary Phosphomolybdate and Pyridyl Ligands

摘要

Organic-inorganic hybrids have attracted great interests in many fields of sciences due to their outstanding properties. Polyoxometalates (POMs) are a class of anionic metal oxide clusters, and their structures and properties can be modified at atomic level. In particular, lacunary POMs possess highly reactive vacant sites and can act as structurally well-defined building blocks. In this work, we report the synthesis of organic-inorganic hybrids based on a lacunary POM and pyridyl ligands in organic media.