RECOVERY FROM LOSS OF REDUCTANT FEED TO A U/PU SEPARATION CONTACTOR, MAGNOX REPROCESSING PLANT, SELLAFIELD

摘要

Following a revealed sustained loss of reductant feed to the Primary Separation 4 (PS4) U/Pu separation contactor in the Magnox Reprocessing Plant in 2014 the solvent extraction cycles were safely shutdown. However, initial mass balance calculations indicated that over four times the typical mass of Pu could be present in PS4. Due to the loss of reductant feed, much of this Pu was expected to be in the solvent phase of Tributyl Phosphate and Odourless Kerosene (TBP/OK) where it would be difficult to observe with the neutron monitors located under PS4. Samples were taken of the solvent in PS4 which confirmed the presence of Pu in solvent; normally almost all of the Pu in PS4 is in the aqueous phase. The volume ratio of solvent to aqueous in the PS4 contactor is high. This meant that simply re-dosing PS4 with reductant could not be supported as a recovery option due to the potential to realise high Pu concentrations in the aqueous phase. This paper details the recovery options which were considered and the ultimate decision to recover PS4 using Gadolinium (Gd) poisoning and Gd-dosed reductant feeds. The recovery included: ? The need to consider the impact of Gd poisoning on monitoring of the recovery with the PS4 neutron monitors ? Close support from criticality safety personnel on the plant at all times during the recovery ? Production of operator aids and short fit for purpose safety documentation to assist with the recovery. The recovery of PS4 proceeded safely and smoothly. There were no losses of Pu to raffinate streams despite the prolonged shutdown. The plant was then safely rundown to flush out residual Pu and Gd.