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Sorption of CO_2 and integrity of a caprock shale

机译:对Co_2的吸附和脚轮页岩的完整性

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CCS is a well-studied technology to efficiently reduce anthropogenic CO_2 from the atmosphere, which is believed to be one of the main factors contributing to global warming. In this paper, we investigate possible changes in the mechanical properties of a shale caprock, when in contact with injected CO_2. Through diffusion, and concentration gradient, the injected CO_2 mixes with the caprock pore fluid, modifying its pH from basic to acid. Different experiments are performed to demonstrate the effect of CO_2 on mechanical properties of the North Sea Draupne shale caprock. The sample was exposed to CO_2-sat brine for about 20 days under a confining pressure of 20 MPa and a pore pressure of 10 MPa. The poroelastic properties such as Young's modulus, Poisson's ratio, bulk modulus as well as the strength were then measured. Even if a slight increase is observed on the strength, this early-age effect of CO_2 on Draupne shale seems very little and is within the experimental error. The results of P-wave velocity measurements reveal a possibility that CO_2 may be coming out of solution during the test. In order to address this possibility, the experimental conditions are being reviewed and continuous measurements (every minute) of Young's modulus and Poisson's ratio are performed onthe sample from consolidation to failure, through the flowing of CO_2-undersaturated brine.
机译:CCS是一项良好的技术,可有效地减少大气中的人为CO_2,这被认为是有助于全球变暖的主要因素之一。在本文中,我们在与注入的CO_2接触时调查页岩谱系的机械性能的可能变化。通过扩散和浓度梯度,注射的CO_2与脚克骨孔流体混合,将其pH从基础上改变为碱。进行不同的实验以证明CO_2对北海Draupne页岩座的机械性能的影响。将样品在20MPa的限制压力下暴露于CO_2-SAT盐水约20天,并为10MPa的孔隙压力。然后测量杨氏模量,泊松比,散装模量以及强度等孔弹性性质。即使在力量上观察到轻微增加,Co_2对Draupne页岩上的这种早期影响似乎很少,并且在实验误差范围内。 P波速度测量的结果揭示了在测试期间可以从溶液中出来的可能性。为了解决这种可能性,正在审查实验条件,并且通过流动CO_2缺盐盐水,对杨氏模量和泊松比的连续测量(每分钟)进行延续测量(每分钟)。

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