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EXPANDING THE ENVELOPE OF FOAMED POLYOLEFIN ELASTOMERS

机译:扩展泡沫聚烯烃弹性体的包络

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The material of choice in the foam industry for many years was Ethylene-Vinyl Acetate copolymers (EVA). This dominance was based on its flexibility, adhesion performance, and foaming window. In the last ten years, ethylene-α-olefin inter-polymers (or Polyolefin Elastomers (POE)) have been integrated in foam formulations as a means to increase processability and cost efficiency. In recent years, the discovery of INFUSE~(TM) Olefin Block Copolymers (OBC’s) has increased the benefits of using ethylene-α-olefin inter-polymers in foam applications. This paper shows that the characteristics that make INFUSE~(TM) OBC’s of interest in Crosslinked (XL) foam systems are increased softness, improved shrinkage, and compression set resistance at elevated temperatures. The paper also shows that OBC foams long- term fatigue behavior departs from that of EVA and POE foams with the same cure state. The room temperature data allowed one to draw the following conclusions: (i) OBC foams showed a more elastic response than EVA and POE as demonstrated by lower final strain and faster recovery after dynamic testing; the elastic response of OBC foams was attributed to its block architecture, and (ii) materials based on short-chain branching (OBC and POE) seemed to recover faster than the foam based on highly branched EVA.
机译:多年来,泡沫行业的选择材料是乙烯 - 乙酸乙烯酯共聚物(EVA)。这种优势是基于其灵活性,粘附性能和发泡窗口。在过去的十年中,乙烯-α-烯烃聚合物(或聚烯烃弹性体(POE))已经整合在泡沫制剂中,作为提高加工性和成本效率的方法。近年来,发现注入〜(TM)烯烃嵌段共聚物(OBC)增加了在泡沫应用中使用乙烯-α-烯烃间聚合物的益处。本文表明,在升高的温度下,使Infradind(XL)泡沫系统感兴趣的感兴趣的感兴趣的特性是增加的柔软性,改进的收缩和压缩设定电阻。本文还表明,OBC泡沫的长期疲劳行为从EVA和PoE泡沫中脱离了同样的固化状态。室温数据允许其中一个得出以下结论:(i)OBC泡沫显示比EVA和PoE更具弹性响应,如较低的最终菌株和动态测试后更快的恢复; OBC泡沫的弹性响应归因于其块体系结构,(II)基于短链分支(OBC和POE)的材料似乎恢复得比高度分支的EVA泡沫快。

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