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Second-order Kinetic Model for the Sorption of Cu(II) Ions in Aqueous Solutions of Zeolite NaA

机译:沸石水溶液中Cu(II)离子吸附的二阶动力学模型

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In this study, the sorption of Cu(II) ions in aqueous solutions of Zeolite NaA by performing batch kinetic sorption experiments. The equilibrium kinetic data were analyzed using the pseudo-second-order kinetic model. A comparison was made of the linear least-squares method and nonlinear method of the widely used pseudo-second-order kinetic model for the sorption of Cu(II) ions of Zeolite. Four pseudo-second-order kinetic linear equations are discussed. Kinetic parameters obtained from the four kinetic linear equations using the linear method differed but they were the same when using the non-linear method. Kinetic parameters obtained from four kinetic linear equations using the linear method differed. Equation type 1 pseudo-second-order kinetic model very well represented the kinetic of the adsorption Cu(II) ions by Zeolite NaA. Equation type 4 exhibited the worst fit. Present investigation showed that the non-linear method may be a better way to determine the kinetic parameters.
机译:在该研究中,通过进行批量动力学吸附实验,通过进行沸石NAA水溶液中Cu(II)离子的吸附。使用伪二阶动力学模型分析平衡动力学数据。广泛使用的伪二阶动力学模型的线性最小二乘法和非线性方法进行了比较,用于沸石Cu(II)离子的吸附。讨论了四个伪二阶动力学线性方程。使用线性方法的四个动力学方程获得的动力学参数不同,但使用非线性方法时它们是相同的。使用线性方法的四个动力学方程获得的动力学参数不同。等式1型伪二阶动力学模型非常好地表示沸石NAA的吸附Cu(II)离子的动力学。方程式4表现出最糟​​糕的合适。目前的研究表明,非线性方法可能是确定动力学参数的更好方法。

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