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Synthesis and Evaluation of Starch Graft Copolymer Applied as Dispersant in Coal-Water Slurry

机译:淀粉接枝共聚物作为分散剂在煤水浆中的合成与评价

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In this paper, a starch-based dispersant for Chinese Shenhua coal-water slurry (CWS) was synthesized by radical polymerization using styrene sulfonate and acrylic acid as graft monomers in oxidation-reduction initiator system. Chemical structure and thermal performance of the copolymer were investigated by Fourier Transform Infrared Spectrum (FT-IR) and Thermogravimetric Analyzer (TGA). The rheological characteristics of the slurry were studied by varying dispersant dosage and shear rate, and the results show, At coal concentration of 66 wt%, dispersant dosage of 0.4 wt% and shear rate of 100 s~(-1), the CWS gives the minimum viscosity of 848 mPa·s. Bleeding ratio tests indicate the dispersant can stabilize the slurry. Based on the above, the starch-based dispersant has due structure and a bright prospect for the application for CWS.
机译:本文采用苯乙烯磺酸盐和丙烯酸作为氧化氧化引发剂体系中的移植式单体,通过自由基聚合合成了用于中国神化煤水浆料(CWS)的淀粉基分散剂。通过傅里叶变换红外光谱(FT-IR)和热重分析仪(TGA)研究了共聚物的化学结构和热性能。通过改变分散剂剂量和剪切速率研究浆料的流变特性,结果表明,在煤浓度为66wt%,分散剂剂量为0.4wt%,剪切速率为100 s〜(-1),Cws给出最小粘度为848MPa·s。出血比试验表明分散剂可以稳定浆料。基于以上,基于淀粉的分散剂具有适当的结构和用于CWS施用的明亮前景。

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