A novel Metal-Organic Framework with pcu topology constructed from cadmium and 1,4-diaza-bicyclo2.2.2octane-N,N'-dioxide

摘要

A novel three dimensional metal-organic framework,Cd(N2C6H_(12))3·2(NO3)(JUC-43,JUC:Jilin University,China),has been synthesized under mild conditions;the single-crystal X-ray diffraction revealed that polymer JUC-43 had a non-interpenetrated pcu topology and the ligand dabco(1,4-diaza-bicyclo[2.2.2]octane)was oxidated in situ to 1,4-diaza-bicyclo[2.2.2]octane-N,N'-dioxide.