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Numerical Simulation of Ion Drift within Ion Mobility Spectrometers in High Peclet Conditions using FEM Techniques

机译:使用FEM技术的离子迁移光谱仪离子漂移的数值模拟

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The goal of this paper is to model and simulate the transport of ions through a miniaturised drift tube of ion mobility spectrometer (IMS). In the first part of this work we test and compare three numerical methods to solve the transient diffusion-advection equation in high Peclet conditions. These methods are the following: Streamline upwind Petrov Galerkin (SUPG), the modified-PDE (MPDE) and the finite calculus method (FIC). In the second part we use the last two numerical methods to study ion transport in a one-dimensional IMS model. Ion peak broadening effects, namely coulombic repulsion, diffusion, transport of two ionic species, have been explored for different initial conditions.
机译:本文的目的是通过离子迁移光谱仪(IMS)的小型化漂移管来模拟和模拟离子的传输。在这项工作的第一部分,我们测试并比较三种数值方法来解决高Peclet条件下的瞬态扩散 - 平面方程。这些方法如下:简化Upwind Petrov Galerkin(Supg),改性PDE(MPDE)和有限微积分(FIC)。在第二部分中,我们使用最后两种数值方法来研究一维IMS模型中的离子传输。对于不同的初始条件,已经探讨了离子峰扩大效果,即库仑排斥,扩散,两种离子物质的运输。

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