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Ge and GeO_x films as sacrificial layer for MEMS technology based on piezoelectric AlN: etching and planarization processes

机译:基于压电ALN的MEMS技术GE和GEO_X薄膜作为MEMS技术的牺牲层:蚀刻和平坦化过程

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In this article we present a study of deposition and etching techniques of germanium (Ge) and amorphous oxygen germanium (GeO_x) films, with the aim of using them as sacrificial layer in the fabrication of AlN-based MEMS by surface micromachining processes. The Ge and GeO_x layers were deposited by RF magnetron sputtering in Ar and Ar/O_2 atmospheres. By controlling the process parameters we were able to set the final composition of the GeOx films, which was assessed by FTIR measurements. We have studied the etch rates of GeO_x films with x ranging from 0 to 1 in H_2O_2 and H_2O_2/acid solutions. Depending on the etching temperature and the oxygen content in the layers, etch rates ranging from 0.2 to 2 μm/min were obtained. Nearly stoichiometric germanium oxide (GeO_2) was etched in pure H_2O at very high rate ( >1 μm/min at room temperature). We have also developed a chemomechanical polishing (CMP) process for the planarization of Ge and GeO_x. The influence of the slurries containing diverse powders (CeO_2, Al_2O_3) and chemical agents (NH_4OH, HCl), the different pads, and the various process parameters on the removal rate and the final sample topography has been studied. Finally, we have analysed the compatibility of the materials involved in the process flow with the processes of planarization and removal of the sacrificial layers.
机译:在本文中,我们介绍了锗(Ge)和无定形氧锗(Geo_x)膜的沉积和蚀刻技术的研究,目的是通过表面微机械加工方法使用它们作为牺牲层的制造中的牺牲层。在AR和Ar / O_2气氛中,通过RF磁控管溅射沉积GE和GEO_X层。通过控制进程参数,我们能够设定Geox膜的最终组成,由FTIR测量评估。我们研究了在H_2O_2和H_2O_2 /酸溶液中的0至1的X蚀刻速率。根据层中的蚀刻温度和氧含量,获得的蚀刻速率范围为0.2至2μm/ min。在纯H_2O中以非常高的速率(室温>1μm/ min)在纯H_2O中蚀刻几乎化学计量锗氧化物(GEO_2)。我们还开发了一种用于GE和GEO_X的平坦化的化学力学抛光(CMP)过程。研究了含有各种粉末(CeO_2,Al_2O_3)和化学试剂(NH_4OH,HCl),不同垫和各种工艺参数的浆料对去除率和最终样品形貌的影响。最后,我们已经分析了过程流程所涉及的材料的兼容性,其具有平坦化和去除牺牲层的过程。

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