Radiative B decay B-bar~0 → D~(0*)γ is studied in the framework of perturbative QCD approach. The short distance (SD) contribution is computed by using B and D~* wave function which is consistent with heavy quark symmetry and valence quark picture. The branching ratio is predicted and it is as small as 10~(-8). In addition to color suppression and helicity suppression due to charm quark mass, it is suppressed by Sudakov factor.
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