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INNOVATIVE SINGLE STEP PREPARATION METHOD OF Pt SUPORTED CARBON FIBERS ELECTRODES FROM LIGININ BY ELECTROSPINNING

机译:通过静电纺丝通过木质素的PT支持碳纤维电极的创新单步制备方法

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The development of high-value products from lignocelullosic materials as lignin, which is the second most abundant carbon feedstock and an important co-product in many lignocellulosic biomass-derived industries, could suppose a significant opportunity to reduce their costs and environmental impacts. Lignin is an attractive raw material for "waste-refinery" or "biorrefinery" [1], and its high aromaticity makes it suitable to be used as precursor of carbon materials. Carbon fibers (CFs) have many advantages over granular carbon and pellets, and show good flexibility, density, high surface area and, in some cases, excellent electrical conductivity [2]. In fact, as a continuous material, the conductivity of the fiber is much higher than the conductivity of grains obtained from the same precursor [3]. These properties make CFs one of the best conformations of carbon for electrochemical applications. Despite CFs can be prepared by different ways, the electrospinning method easily allows to obtaining a binderless carbon electrode from a precursor solution [3]. In addition to the good structural characteristics of CFs, by this method, it is possible to obtain a uniform dispersion of a metal throughout the fibers, in a single step, yielding a carbon fiber with metallic platinum after suitable thermal stabilization and carbonization stages [4]. In this work, we present a straightforward method to obtaining, in a single step, CFs with good structural properties and very well dispersed platinum nanoparticles and P surface groups by electrospinning, to be used as binderless electrodes for different applications.
机译:Lignocellullosic材料的高价值产品的发展是木质素,这是许多木质纤维素生物量衍生产业中的第二个最丰富的碳原料和重要的共同产品,可能会发现降低成本和环境影响的重要机会。木质素是“废物炼油厂”或“生物术”[1]的有吸引力的原料,其高芳香性使其适合用作碳材料的前体。碳纤维(CFS)对颗粒碳和颗粒具有许多优点,并且在某些情况下显示出良好的柔韧性,密度,高表面积,以及优异的导电性[2]。事实上,作为连续材料,纤维的电导率远高于来自相同前体获得的晶粒的导电性[3]。这些属性使CFS成为电化学应用的最佳碳的最佳构象之一。尽管可以通过不同的方式制备CFS,但静电纺丝方法容易允许从前体溶液中获得粘合剂碳电极[3]。除了CFS的良好结构特征之外,通过该方法,在单一的步骤中可以在整个纤维中获得均匀的金属分散,在合适的热稳定和碳化阶段之后产生金属铂的碳纤维[4 ]。在这项工作中,我们提出了一种直接的方法,以便在单一的步骤中获得具有良好结构性质的CF和通过静电纺丝通过良好的结构性能和非常好的分散的铂纳米颗粒和P表面基团,以用作不同应用的粘合剂电极。

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