ANALYSIS OF CO_2 CAPTURE FROM POWER-PLANT FLUE GAS USING THE MEMBRANE GAS ABSORPTION (MGA) METHOD

摘要

Currently membrane gas absorption (MGA) is a novel approach for gas separation. In the present work, a wide-ranging 2D mathematical model for CO_2 absorption from the N_2/CO_2 mixture is proposed. Single solvents [H_2O, ethylenediamine (EDA), diethanolamine (DEA), monoethanolamine (MEA), piperazine (PZ)] and blended solvents [DEA/PZ] were used as the absorbents. The non-wetting mode for the membrane contactor was considered in the calculations. The effects of gas concentration and velocity, and liquid concentration and velocity on CO_2 removal were observed. The simulation results were verified with the experimental data showing a good agreement. The modeling results indicate that gas concentration and velocity have a negative effect on the capture process, while liquid concentration and velocity enhance CO_2 capture. Also, it is noted that PZ has the best absorption performance than other single absorbents. The chemical solvents are much better than the physical solvent for the absorption of CO_2. For mixed absorbents based on amine solutions, the CO_2 removal efficiency could be about 20% higher than that of the single solutions. Thus, this model could provide the optimum operating conditions for acid gas absorption in the hollow fiber membrane module. It is also proved that the MGA approach exhibits a good potential in power-plant waste gas purification.