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Study on Nitrate Removal with Nanoscale Zero-valent Iron Prepared by Hydrogen Reduced Goethite

机译:氢还原针铁矿制备的纳米零价铁去除硝酸盐的研究

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It is well-known that nanoscale zero-valent iron (NZVI)has the high activity for nitrate removal,therefore,this paper carried out NZVI(14nm)prepared by hydrogen reduced natural goethite,then investigate the effect factors of nitrate removal,like initial pH value,nitrate concentration,dissolved oxygen(DO),iron-to-nitrate ratio,natural goethite grain size, and compare it with ordinary zero-valent iron (OZVI) through the static experiment.Results indicate that NZVI has little effect on the initial pH value during nitrate removal when compared with OZVI,and the removal rate of 90% within 5h was obtained for NZVI in reducing nitrate when iron-to-nitrate ratio was 40:1,and the nitrate concentration was 60mg/L. No nitrite was detected during the process.
机译:众所周知,纳米零价铁(NZVI)具有很高的去除硝酸盐的活性,因此,本文采用氢还原天然针铁矿制备了NZVI(14nm),然后研究了硝酸盐去除的影响因素。 pH值,硝酸盐浓度,溶解氧(DO),铁硝比,天然针铁矿晶粒尺寸,并通过静态实验将其与普通零价铁(OZVI)进行比较。结果表明NZVI对锌的影响很小与OZVI相比,硝酸盐去除过程中的初始pH值较高;在铁与硝酸盐之比为40:1,硝酸盐浓度为60mg / L的情况下,NZVI在还原硝酸盐后5h内去除率达到90%。在此过程中未检测到亚硝酸盐。

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