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Preparation of octobultoxy-2,3-naphthalocyanine copper and the gas sensitivity of its LB film

机译:八溴氧基-2,3-萘菁铜的制备及其LB膜的气敏性

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The title complex octobultoxy 2,3-naphthalocyanine copper (II)[CoNc(OC_4H_9)_8] was sythesized, and its stable langmuir film was obtained on the pure water surfase. The molecular area and the collapse pressure are 74 A and 55mN/m respectively. The LB film is sensitive to NH_3 (80-200 ppm), methol (10-50ppm), alcohol (10-50ppm), isopropanol (10-50ppm) at room temperature. The sensitivity is increased with the carbon number of alcohol increasing at the same concentration of gas.
机译:合成了标题配合物八溴氧基2,3-萘酞菁铜(II)[CoNc(OC_4H_9)_8],并在纯水表面上获得了稳定的朗缪尔膜。分子面积和塌陷压力分别为74 A和55mN / m。 LB膜在室温下对NH_3(80-200 ppm),甲醇(10-50ppm),醇(10-50ppm),异丙醇(10-50ppm)敏感。在相同的气体浓度下,酒精中碳原子数的增加会增加灵敏度。

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