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Methods for Determining the Amount of Hydrates Formed During Blowdown of Natural Gas Compressor Station

机译:测定天然气压缩机站排污过程中形成的水​​合物量的方法

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Natural gas hydrates could form during blowdown of compressor station yard piping, even if the moisture composition is within the allowable range of up to 65 mg/st.m~3. This is because the temperature of the gas drops well below the vapour-hydrate equilibrium. If sufficient hydrates form, they have the potential to impede the path of the gas to the blowdown stack exit. To evaluate this risk, it is important to determine the conditions at which hydrates could form under gas blowdown situations and accurately determine the quantity that would form as both gas pressure and temperature drop during the blowdown process. This paper first compares the hydrate equilibrium conditions for different moisture contents obtained with a publicly available model to published measured data for some alkanes present in natural gas. A gas blowdown scenario establishing the gas conditions (P and T) is then presented based on the worst case scenario of adiabatic expansion of the gas. Based on these conditions, two methods are developed to quantify the amount of hydrates that could form during the blowdown process. These methods are demonstrated on a gas blowdown event of compressor station discharge yard piping where the gas was assumed to have moisture contents of 65 mg/st.m3. The potential amount of hydrates formed and the implications on the gas path to blowdown exit are discussed.
机译:即使水分含量在最高65 mg / st.m〜3的允许范围内,也可能在压缩机站场管道的排污期间形成天然气水合物。这是因为气体的温度下降到远低于蒸气水合物平衡的水平。如果形成足够的水合物,它们有可能阻碍气体进入排污烟囱出口的路径。为了评估这种风险,重要的是确定在气体排泄情况下水合物形成的条件,并准确确定在排泄过程中随着气体压力和温度下降而形成的水合物的量。本文首先将使用公开可用的模型获得的不同水分含量的水合物平衡条件与公开的天然气中存在的某些烷烃的测量数据进行比较。然后根据绝热气体膨胀的最坏情况,提出确定气体条件(P和T)的放气情况。基于这些条件,开发了两种方法来定量排污过程中可能形成的水合物数量。这些方法在压缩机站卸料场管道的气体排泄事件中得到了证明,假设该气体的水分含量为65 mg / st.m3。讨论了潜在的水合物形成量以及对排污口气路的影响。

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