Crushing, Pelletizing and Alkaline Leaching of Massive Low Grade Zinc Oxide Ores

摘要

The percentage of leached zinc in massive zinc oxide ores (11.7% Zn,＞2 mm) is up to 73.3 % in 120 days. Alternatively, crushed to -0.154 mm, mixed with cement 5% (wt), pelletized and solidified. The diameters of the pellets obtained are between 5 mm to 8 mm. When the pellet solidification periods are 3 days, 10 days and 45 days respectively, the alkaline leaching rates of zinc in the pellets are up to 95.8%, 89.1% and 76.4% respectively. Decreasing the solidification time can reduce reaction time, increase dissolution of zinc in pellets and lower the effect of initial zinc concentration on leaching rate. The experiment results show that the minimum solidification time is three days, and the kinetic study indicates that alkaline leaching of the low grade zinc oxide pellets is controlled by the diffusion of the leach liquor through the gangue layer in the whole leach process,and the apparent rate constants are 3.33×10-2 day-1, 9.18×10-3 day-1, 5.82×10-3 day-1 respectively.