Influence of vulcanization agents on the rheological behavior of polypropylene (PP)/styrene-butadiene-styrene copolymer (SBS) blends

摘要

The rheological behavior of Polypropylene (PP) modified with Styrene-Butadiene-Styrene copolymer (SBS), within the composition range of 10-40 wt % SBS content, was studied based on blend ratio, vulcanization agents (sulphur, peroxide) and curing times. The rubber phase was statically cured and blends with PP were mixed in a twin screw extruder. Results indicate all unvulcanized systems show an increasing melt viscosity on SBS content. Regarding vulcanizing agents, sulphur shows no variation on melt viscosity neither with shear strain nor with curing time, while peroxide shows significant changes on melt viscosity at low shear strain ranges when varying curing times from 2 to 6 mm.