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Preparation and Corrosion Resistance of Rare Earth Ceramic Film on AZ91 Magnesium Alloy

机译:AZ91镁合金上稀土陶瓷膜的制备及耐蚀性

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摘要

With the purpose of improving corrosion resistance and solving environmental pollution caused by traditional protective technique, rare earth ceramic film on AZ91 magnesium alloy was prepared by dip coating process, and technical parameters of preparation were defined. Microstructure and composition of the film were studied and corrosion resistance was evaluated as well. The results show that rare earth ceramic film is uniform, dense, with strong cohesion and intact coverage. The film is mainly made up of CeO_2 and MgCeO_3. The results of corrosion experiments approve that the film acts as a barrier to isolate the contact of the substrate with corrosion media and decreas corrosion rate. Polarization curve of the coated sample shiftes to positive potential obviously, corrosion current density declines from 12 to 0. 2 mA·cm~(-2) and polarization resistance increases from 100 to 2. 7 x 10~4 Ω. These facts indicate that rare earth ceramic film could effectively improve corrosion resistance of AZ91 magnesium alloy.
机译:为了提高耐蚀性,解决传统保护技术对环境的污染,采用浸涂法制备了AZ91镁合金稀土陶瓷膜,并定义了制备工艺参数。研究了薄膜的微观结构和组成,并评估了其耐腐蚀性。结果表明,稀土陶瓷膜均匀,致密,内聚力强,覆盖完整。薄膜主要由CeO_2和MgCeO_3组成。腐蚀实验的结果表明该膜可作为隔离层,以隔离基材与腐蚀介质的接触并降低腐蚀速率。涂膜样品的极化曲线明显移向正电位,腐蚀电流密度从12下降到0。2mA·cm〜(-2),极化电阻从100上升到2。7 x 10〜4Ω。这些事实表明,稀土陶瓷膜可以有效地改善AZ91镁合金的耐蚀性。

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