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Thermal Curing and Environmental Impact of Alkali-Activated Cementitious Materials

机译:碱活化胶凝材料的热固化和环境影响

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During the production of ordinary Portland cement (OPC) clinker a lot of carbon dioxide (CO_2 ) is emitted. To improve the sustainability of concrete production, many studies were carried out to evaluate alternative binders for OPC. The use of alkali-activated cementitious materials (AAMs) reduces the amount of Portland cement clinker and a larger volume of industrial by-products such as fly ash (FA) and blast furnace slag (BFS) can be applied. The combination of an aluminosilicate precursor and an alkali activator is characterised by a slower early age strength development compared to OPC. Thermal curing of the concrete is a successful technique to overcome this drawback. Although, thermal curing promotes the early age strength development of OPC-based concrete, the strength at 28 days often is relatively lower. In terms of environmental impact of AAMs, a significant reduction in production-related CO_2 -emissions is possible by replacing OPC by FA and/or BFS. With a relatively small activator dosage, it was found that the CO_2 -emissions can be decreased by up to 85% for AAMs compared to OPC-based mixtures. In this research, the effect of the mix design and curing temperature on the early age strength development and the environmental impact of AAMs was investigated.
机译:在普通波特兰水泥(OPC)熟料的生产过程中,会排放大量二氧化碳(CO_2)。为了提高混凝土生产的可持续性,进行了许多研究以评估OPC的替代粘合剂。碱活化胶凝材料(AAM)的使用减少了波特兰水泥熟料的数量,可以使用大量工业副产品,例如粉煤灰(FA)和高炉矿渣(BFS)。与OPC相比,硅铝酸盐前体和碱活化剂的组合具有较慢的早期强度发展的特征。混凝土的热固化是克服此缺点的成功技术。尽管热固化促进了OPC基混凝土的早期强度发展,但28天的强度通常相对较低。就AAM的环境影响而言,通过用FA和/或BFS代替OPC,可以显着减少与生产相关的CO_2排放。发现使用相对较小的活化剂剂量,与基于OPC的混合物相比,AAM的CO_2排放量最多可以降低85%。在这项研究中,研究了混合料设计和固化温度对AAMs早期强度发展和环境影响的影响。

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