Search for new red phosphors under NUV/blue excitation - the stimulating future for solid state lighting

摘要

Research on down conversion phosphor materials is the key for the development of solid state lighting (SSL). Especially finding alternative red phosphor for white LEDs based on blue or NUV LEDs are important research task. Under this view, we have synthesized a series of Eu~(3+) substituted La_2W_(2-x)Mo_xO_9 (x = 0 ～ 2, insteps of 0.1) red phosphor and characterized by X-ray diffraction (XRD) and photoluminescence. XRD results reveal a phase transition from triclinic to cubic structure for x ≥ 0. All the compositions show broad charge transfer band due to charge transfer from oxygen to tungsten/molybdenum and red emission due to Eu~(3+) ions. Select compositions show high red emission intensity compared to the commercial red phosphor under NUV/blue ray excitation. Hence, this candidate can be possible red emitting phosphors for white LEDs.