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A molecularly imprinted polymer conjugated cobalt oxide nanoparticle based screen printed sensor for enhanced sensing of chlorpyrifos

机译:基于分子印迹聚合物共轭氧化钴纳米粒子的丝网印刷传感器,用于增强毒死rif的感测

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) nanoparticles have enhanced the response of the SPCEs as compared to the unmodified one. The polymerization of pyrrole in the presence of the template molecule has exhibited the detection of CP of the order of parts per billion (ppb). Electrochemical properties of the developed sensor were characterized by means of cyclic voltammetry (CV) and differential pulse voltammetry (DPV), respectively. In its first phase of development, the SPCEs coated MIP based sensor was found to distinguish different concentrations of CP successfully and exhibited a linear range from 0.1 ppb to 100 ppb of CP. Selectivity studies also revealed that the sensor can detect the target analyte efficiently in the presence of other interferents. These results paved the way for the further advancement of the sensor regarding the detection of CP for real-time applications.
机译:与未修饰的纳米粒子相比,纳米粒子增强了SPCE的响应。在模板分子存在下,吡咯的聚合反应显示出对CP的检测约为十亿分之几(ppb)。分别通过循环伏安法(CV)和差分脉冲伏安法(DPV)表征了开发的传感器的电化学性能。在其开发的第一阶段,发现基于SPCEs涂层MIP的传感器能​​够成功地区分不同浓度的CP,并表现出0.1 ppb至100 ppb的线性范围。选择性研究还表明,该传感器可以在存在其他干扰物的情况下有效地检测目标分析物。这些结果为传感器在实时应用中检测CP的进一步发展铺平了道路。

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